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News

Electrolyte containing nanocrystals raises fuel cell efficiency

Delft University Of Technology : 04 April, 2011  (Technical Article)
The addition of extremely small crystals to solid electrolyte material has the potential to considerably raise the efficiency of fuel cells. Researchers at TU Delft were the first to document this accurately, and their second article on the subject in a very short time has now been published in the scientific journal, Advanced Functional Materials.
Researchers at the Faculty of Applied Sciences at TU Delft have been concentrating their efforts on improving electrolyte materials. The better the characteristics of the electrolyte, the better, more compactly or more efficiently the fuel cell or battery works.

The electrolyte is usually a liquid, but this has a number of drawbacks. The liquid has to be very well enclosed, for example, and it takes up a relatively large amount of space. “It would therefore be preferable to have an electrolyte made of solid matter,” says Lucas Haverkate. “Unfortunately though, that has disadvantages as well. The conductivity in solid matter is not as good as it is in a liquid.”

“In a solid matter you have a network of ions, in which virtually every position in the network is taken. This makes it difficult for the charged particles (protons) to move from one electrode to another. It’s a bit like a traffic jam on a motorway. What you need to do is to create free spaces in the network.”

One of the ways of achieving this, and therefore of increasing conductivity in solid electrolytes, is to add nanocrystals (of seven nanometres to around fifty nanometres), of Titanium Dioxide in this case. “A characteristic of these TiO2 crystals is that they attract protons, and this creates more space in the network. The nanocrystals are mixed in the electrolyte with a solid acid (CsHSO4). This latter material ‘delivers’ the protons to the crystals. The addition of the crystals appears to cause an enormous leap in the conductive capacity, up to a factor of 100,” concludes Haverkate.

Fellow PhD student, Wing Kee Chan, is the main author of a second item that appeared in the same publication. Chan focused on the experimental side of the research.

Chan carried out measurements on the electrolyte material using the neutron diffraction method. This involves sending neutrons through the material. The way in which the neutrons are dispersed makes it possible to deduce certain characteristics of the material, such as the density of protons in the crystals. “It is the first time that measurements have been taken of solid-material electrolytes in this way, and on such a small scale. The fact that we had nuclear research technologies at the Reactor Institute Delft at our disposal was tremendously valuable,” said Haverkate.

However, the combination of TiO2 and CsHSO4 does not mark the end of the search for a suitable solid-material electrolyte. Other material combinations will be tested that may achieve better scores in the area of stability, for example. “At this stage, we are more concerned about acquiring a fundamental understanding and a useful model, than the concrete issue of finding out what the most suitable material is. It is important that we identify the effect of nanocrystals, and give it a theoretical basis. I think there is great potential for these electrolytes. They also have the extra benefit of continuing to function well over a wide range of temperatures, which is of particular relevance for applying them in fuel cells, ” says Professor Fokko Mulder.

* Full bibliographic information
Wing K. Chan, Lucas A. Haverkate, Wouter J.H. Borghols, Marnix Wagemaker, Stephen J. Picken, Ernst R.H. van Eck, Arno P.M. Kentgens, Mark R. Johnson, Gordon J. Kearley, Fokko M. Mulder. Direct View on Nanoionic Proton Mobility. Advanced Functional Materials. 24 March 2011.

Wing K. Chan, Lucas A. Haverkate, Wouter J.H. Borghols, Marnix Wagemaker, Stephen J. Picken, Ernst R.H. van Eck, Arno P.M. Kentgens, Mark R. Johnson, Gordon J. Kearley, Fokko M. Mulder. Direct View on Nanoionic Proton Mobility. Advanced Functional Materials. 24 March 2011.

Lucas A. Haverkate, Wing K. Chan, Fokko M. Mulder. Ionic Nanosystems: Large Space-Charge Effects in a Nanostructured Proton Conductor. Advanced Functional Materials. 9 December 2010.

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